WestCHEM, School of Chemistry, The University of Glasgow, Glasgow, G12 8QQ, UK.
Chem Commun (Camb). 2016 Jul 12;52(58):9109-12. doi: 10.1039/c6cc01041e.
We report the preparation and characterization of two new polyoxothiometalate species, {Mo16} = {(Mo2O2S2)8(OH)16(C4O4)2}(4-) (compound 1) and {Mo12} = {(Mo2O2S2)6(OH)12(CH3COO)2}(2-) (compound 2). Control of synthesis is achieved by the addition of the organic-template and further re-arrangement is controlled simply by the addition of potassium to a precursor compound yielding compound 2. The structures of the compounds are discussed and we also show that ion-mobility mass spectrometry can be used to resolve the species and their building blocks in solution.
我们报告了两种新的多氧硫代金属酸盐的制备和表征，{Mo16} = {(Mo2O2S2)8(OH)16(C4O4)2}(4-)（化合物 1）和{Mo12} = {(Mo2O2S2)6(OH)12(CH3COO)2}(2-)（化合物 2）。通过添加有机模板来控制合成，并且通过向前体化合物中添加钾进一步简单地控制重排，得到化合物 2。讨论了化合物的结构，我们还表明，离子迁移质谱可用于在溶液中解析物种及其构建块。
