手性（MoOS）基簇的自发形成由二聚{TeO}-基模板驱动。
Spontaneous formation of a chiral (MoOS)-based cluster driven by dimeric {TeO}-based templates.
机构信息
WestCHEM, School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, UK.
出版信息
Dalton Trans. 2018 May 8;47(18):6283-6287. doi: 10.1039/c8dt00832a.
Utilization of [Mo2S2O2(H2O)6]2+ and a tellurite anion led to the formation of three new clusters, 1-3, with unique structural features. The tellurite anion not only templated the formation of [(Mo2O2S2)4(TeO3)(OH)9]3-1 and [(Mo2O2S2)12(TeO3)4(TeO4)2 (OH)18]10-3, but also the in situ generation of two different types of dimeric {Te2O6} based moieties induced the spontaneous assembly of the chiral [(Mo2O2S2)10(TeO3)(Te2O6)2(OH)18]8- anionic cluster, 2.
利用[Mo2S2O2(H2O)6]2+和碲酸盐阴离子合成了三个具有独特结构特征的新型簇合物 1-3。碲酸盐阴离子不仅模板合成了[(Mo2O2S2)4(TeO3)(OH)9]3-1 和 [(Mo2O2S2)12(TeO3)4(TeO4)2 (OH)18]10-3，而且原位生成的两种不同类型的基于 {Te2O6} 的二聚体诱导了手性 [(Mo2O2S2)10(TeO3)(Te2O6)2(OH)18]8-阴离子簇合物 2 的自发组装。
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