Tang Xiaolong, Xu Xianmang, Yi Honghong, Chen Chen, Wang Chuan
College of Environmental Science and Engineering, Kunming University of Science & Technology, Kunming 650093, China.
ScientificWorldJournal. 2013 Jul 16;2013:463160. doi: 10.1155/2013/463160. eCollection 2013.
Electrochemical promotion of catalysis reactions (EPOC) is one of the most significant discoveries in the field of catalytic and environmental protection. The work presented in this paper focuses on the aspects of reaction mechanism, influencing factors, and recent positive results. It has been shown with more than 80 different catalytic systems that the catalytic activity and selectivity of conductive catalysts deposited on solid electrolytes can be altered in the last 30 years. The active ingredient of catalyst can be activated by applying constant voltage or constant current to the catalysts/electrolyte interface. The effect of EPOC can improve greatly the conversion rate of NOx. And it can also improve the lifetime of catalyst by inhibiting its poisoning.
电化学促进催化反应(EPOC)是催化和环境保护领域最重要的发现之一。本文所展示的工作聚焦于反应机理、影响因素以及近期的积极成果等方面。在过去30年中,超过80种不同的催化体系表明,沉积在固体电解质上的导电催化剂的催化活性和选择性可以被改变。通过在催化剂/电解质界面施加恒定电压或恒定电流,可以激活催化剂的活性成分。EPOC效应可以大大提高氮氧化物的转化率,并且还可以通过抑制催化剂中毒来提高其使用寿命。