5,10,15-三对甲苯基三苯并[5,6]环庚三烯自由基的合成与性质。
Synthesis and properties of the 5,10,15-trimesityltruxen-5-yl radical.
机构信息
Department of Chemistry, Massachusetts Institute of Technology , 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.
出版信息
Org Lett. 2013 Sep 20;15(18):4782-5. doi: 10.1021/ol402153w. Epub 2013 Aug 27.
Abstract
The synthesis of a long-lived, truxene-based radical that is highly delocalized and exhibits a narrow EPR absorption is reported. The radical is stable for multiple hours in a solution exposed to air and remains for months in the solid state under inert gas. Characterization and properties are discussed.
摘要
报道了一种长寿命、基于三嗪的自由基的合成，该自由基具有高度离域性和较窄的 EPR 吸收。该自由基在暴露于空气中的溶液中稳定数小时，并在惰性气体下的固态中保持数月。讨论了其特性和性质。
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