CSIRO, Materials Science and Engineering, Bag 10, Clayton South MDC, Victoria, 3169, Australia; Department of Chemical Engineering, Eindhoven University of Technology, Den Dolech 2, Eindhoven, 5612AZ, The Netherlands.
Macromol Rapid Commun. 2014 Feb;35(4):492-7. doi: 10.1002/marc.201300459. Epub 2013 Aug 29.
A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization.
本文报道了一种通用且经济高效的方法，可通过自动化合成仪中的顺序 RAFT 聚合快速、完全无人值守地制备系统准两嵌段共聚物库。该方法通过一锅、顺序、RAFT 聚合合成了具有低分散度的聚（甲基丙烯酸丁酯）-准嵌段-聚（甲基丙烯酸甲酯）的 23 成员库，该库涵盖了第二嵌段的很宽（五倍）摩尔质量范围。
