Department of Chemistry and Chemical Engineering, Faculty of Engineering, Yamagata University, 4-3-16 Jonan, Yamagata, Yonezawa 992-8510, Japan.
Nanoscale Res Lett. 2013 Sep 2;8(1):373. doi: 10.1186/1556-276X-8-373.
Organic-sulfur-zinc hybrid materials were prepared via polycondensation of Zn(OAc)2 and trithiols bearing various alkyl groups. A soluble nanoparticle could be obtained by the polycondensation using a trithiol bearing octadecyl moieties. The good dispersing ability as nano-scaled particles was confirmed by dynamic light scattering and atomic force microscopy analyses. This hybrid nanoparticle was miscible with poly(methyl methacrylate) and served as a refractive additive to increase refractive indexes. The calculated refractive index value for the nanoparticle was 1.58.
通过 Zn(OAc)2 和带有各种烷基的三硫醇的缩聚反应制备了有机硫-锌杂化材料。使用带有十八烷基部分的三硫醇进行缩聚反应可以得到可溶的纳米粒子。通过动态光散射和原子力显微镜分析证实了其作为纳米级粒子的良好分散能力。这种杂化纳米粒子与聚甲基丙烯酸甲酯混溶，并用作折射率添加剂以提高折射率。该纳米粒子的计算折射率值为 1.58。
