Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei Long Road, Shanghai 200237, China.
Chem Commun (Camb). 2013 Oct 21;49(82):9491-3. doi: 10.1039/c3cc45823g.
Three ruthenium complexes bearing backbone-monosubstituted CAACs were prepared and displayed dramatic improvement in catalytic efficiency not only in RCM reaction but also in the ethenolysis of methyl oleate, compared to those bearing backbone-disubstituted CAACs.
三种带有主链单取代 CAAC 的钌配合物被制备出来，与带有主链双取代 CAAC 的配合物相比，不仅在 RCM 反应中，而且在油酸甲酯的乙烯基解聚反应中，显示出催化效率的显著提高。
