• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

通过光控自由基聚合和南极假丝酵母脂肪酶B的酶催化一锅法合成多功能聚合物。

One-Pot Synthesis of Multifunctional Polymers by Light-Controlled Radical Polymerization and Enzymatic Catalysis with Candida antarctica Lipase B.

作者信息

Hrsic Emin, Keul Helmut, Möller Martin

机构信息

Institute of Technical and Macromolecular Chemistry, RWTH Aachen and Interactive Materials Research-DWI an der RWTH Aachen e.V., Forckenbeckstraße 50, D-52056, Aachen, Germany.

出版信息

Macromol Rapid Commun. 2015 Dec;36(23):2092-6. doi: 10.1002/marc.201300512. Epub 2013 Sep 9.

DOI:10.1002/marc.201300512
PMID:24014135
Abstract

The preparation of multifunctional polymers and block copolymers by a straightforward one-pot reaction process that combines enzymatic transacylation with light-controlled polymerization is described. Functional methacrylate monomers are synthesized by enzymatic transacylation and used in situ for light-controlled polymerization, leading to multifunctional methacrylate-based polymers with well-defined microstructure.

摘要

本文描述了通过将酶促转酰基化与光控聚合相结合的直接一锅法反应制备多功能聚合物和嵌段共聚物的方法。通过酶促转酰基化合成功能性甲基丙烯酸酯单体，并将其原位用于光控聚合，从而得到具有明确微观结构的基于甲基丙烯酸酯的多功能聚合物。

相似文献

1
One-Pot Synthesis of Multifunctional Polymers by Light-Controlled Radical Polymerization and Enzymatic Catalysis with Candida antarctica Lipase B.通过光控自由基聚合和南极假丝酵母脂肪酶B的酶催化一锅法合成多功能聚合物。
Macromol Rapid Commun. 2015 Dec;36(23):2092-6. doi: 10.1002/marc.201300512. Epub 2013 Sep 9.
2
Enzyme-catalyzed degradation of biodegradable polymers derived from trimethylene carbonate and glycolide by lipases from Candida antarctica and Hog pancreas.南极假丝酵母脂肪酶和猪胰脂肪酶对源自碳酸三亚甲基酯和乙交酯的可生物降解聚合物的酶催化降解作用
J Biomater Sci Polym Ed. 2012;23(10):1355-68. doi: 10.1163/092050611X581525. Epub 2012 May 8.
3
One-Pot Synthesis of Multifunctional Polymers by Light-Controlled Radical Polymerization and Enzymatic Catalysis with Candida antarctica Lipase B.
Macromol Rapid Commun. 2015 Dec;36(23):2111. doi: 10.1002/marc.201500550.
4
Lipase-catalyzed synthesis of hyperbranched poly-L-lactide in an ionic liquid.在离子液体中脂肪酶催化合成超支化聚 L-丙交酯。
Bioprocess Biosyst Eng. 2013 Mar;36(3):383-7. doi: 10.1007/s00449-012-0792-3. Epub 2012 Aug 7.
5
Enzymatic synthesis of multi-component copolymers and their structural characterization.多组分共聚物的酶促合成及其结构表征。
Mol Divers. 2003;6(3-4):287-95. doi: 10.1023/b:modi.0000006820.04426.97.
6
Kinetic study of Candida antarctica lipase B immobilization using poly(methyl methacrylate) nanoparticles obtained by miniemulsion polymerization as support.以通过细乳液聚合制备的聚甲基丙烯酸甲酯纳米粒子为载体固定化南极假丝酵母脂肪酶B的动力学研究
Appl Biochem Biotechnol. 2015 Mar;175(6):2961-71. doi: 10.1007/s12010-015-1478-5. Epub 2015 Jan 13.
7
Lipase catalyzed HEMA initiated ring-opening polymerization: in situ formation of mixed polyester methacrylates by transesterification.脂肪酶催化甲基丙烯酸羟乙酯引发的开环聚合反应：通过酯交换原位形成混合聚酯甲基丙烯酸酯。
Biomacromolecules. 2008 Feb;9(2):704-10. doi: 10.1021/bm7010449. Epub 2008 Jan 17.
8
Recent Developments and Optimization of Lipase-Catalyzed Lactone Formation and Ring-Opening Polymerization.脂肪酶催化内酯形成及开环聚合的最新进展与优化
Macromol Rapid Commun. 2016 Dec;37(24):1986-2004. doi: 10.1002/marc.201600494. Epub 2016 Nov 2.
9
Stabilization of Lipase in Polymerized High Internal Phase Emulsions.聚合物高内相比乳液中脂肪酶的稳定性。
J Agric Food Chem. 2018 Apr 11;66(14):3619-3623. doi: 10.1021/acs.jafc.8b00894. Epub 2018 Mar 30.
10
Enzymatic synthesis of poly-L-lactide and poly-L-lactide-co-glycolide in an ionic liquid.离子液体中聚 L-乳酸和聚 L-乳酸-共-乙醇酸的酶促合成。
Bioprocess Biosyst Eng. 2010 Jun;33(5):629-38. doi: 10.1007/s00449-009-0388-8. Epub 2009 Nov 4.

引用本文的文献

1
Straightforward Enzymatic Methacrylation of Poly(Glycerol Adipate) for Potential Applications as UV Curing Systems.聚己二酸甘油酯的直接酶促甲基丙烯酸酯化及其在紫外光固化体系中的潜在应用
Polymers (Basel). 2023 Jul 14;15(14):3050. doi: 10.3390/polym15143050.
2
Recent advances in the synthesis of biodegradable polyesters by sustainable polymerization: lipase-catalyzed polymerization.可持续聚合合成可生物降解聚酯的最新进展：脂肪酶催化聚合
RSC Adv. 2020 Oct 1;10(59):36230-36240. doi: 10.1039/d0ra07138b. eCollection 2020 Sep 28.