KOH 催化酯和叔酰胺的还原反应，条件温和、效率高。
Facile and efficient KOH-catalysed reduction of esters and tertiary amides.
机构信息
EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK.
出版信息
Chem Commun (Camb). 2013 Oct 28;49(84):9758-60. doi: 10.1039/c3cc45930f.
PMID:24022085
Abstract
Esters and tertiary amides were efficiently reduced to their corresponding alcohols and amines in high yields under mild and environmentally friendly conditions. The presented KOH-catalysed system involves a simple hydrosilylation procedure that is carried out under solvent-free conditions and does not require the use of inert conditions.
摘要
酯和叔酰胺在温和、环保的条件下高效还原为相应的醇和胺，产率很高。所提出的 KOH 催化体系涉及一种简单的硅氢化反应程序，在无溶剂条件下进行，不需要使用惰性条件。
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