手性金属有机骨架催化芳香胺对消旋环氧的对映选择性开环反应。
Enantioselective ring-opening of meso-epoxides by aromatic amines catalyzed by a homochiral metal-organic framework.
机构信息
Department of Chemistry University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA.
出版信息
Chem Commun (Camb). 2013 Oct 28;49(84):9836-8. doi: 10.1039/c3cc45988h.
PMID:24030658
Abstract
The enantioselective ring-opening of meso-epoxides by aromatic amines was achieved by using a new chiral metal-organic framework . The corresponding α-hydroxyamines were obtained with good yields and ee values (up to 89% ee).
摘要
通过使用新型手性金属有机骨架，实现了芳胺对消旋环氧的对映选择性开环反应。以良好的收率和对映体过量值（高达 89%ee）得到了相应的α-羟基胺。
Zotero 插件