DNA 与镜像 DNA：一种在基于 DNA 的不对称催化中调谐绝对构型的通用方法。
DNA vs. mirror-image DNA: a universal approach to tune the absolute configuration in DNA-based asymmetric catalysis.
机构信息
Laboratoire de Chimie Organique, ESPCI ParisTech, CNRS (UMR 7084), 10 rue Vauquelin, 75231 Paris Cedex 05 (France).
出版信息
Angew Chem Int Ed Engl. 2013 Oct 25;52(44):11546-9. doi: 10.1002/anie.201306232. Epub 2013 Sep 12.
PMID:24030985
Abstract
Mirror mirror on the wall: By taking advantage of the unique structural features of L-DNA, the first examples of left-helical enantioselective induction in the field of DNA-based asymmetric catalysis were realized. Most importantly, this approach is the only one that allows a reliable and predictable access to both enantiomers for any given reaction.
摘要
镜子，镜子，在墙上：通过利用 L-DNA 的独特结构特征，首次在基于 DNA 的不对称催化领域实现了左手性对映选择性诱导。最重要的是，这种方法是唯一一种能够可靠且可预测地获得任何给定反应两种对映异构体的方法。
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