通过分子内傅克烷基化反应来破译基于 DNA 的不对称催化。
Deciphering DNA-based asymmetric catalysis through intramolecular Friedel-Crafts alkylations.
机构信息
Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan.
出版信息
Chem Commun (Camb). 2012 Oct 28;48(84):10398-400. doi: 10.1039/c2cc35625b. Epub 2012 Sep 17.
PMID:22986468
Abstract
We describe asymmetric intramolecular Friedel-Crafts alkylations with a DNA-based hybrid catalyst and propose a plausible binding model. This study shows promise for studying relationships between the helical chirality of DNA and enantioselectivity of the chemical reaction.
摘要
我们描述了基于 DNA 的杂化催化剂的不对称分子内 Friedel-Crafts 烷基化反应，并提出了一个合理的结合模型。这项研究为研究 DNA 螺旋手性与化学反应对映选择性之间的关系提供了可能。
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