Department of Physics, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, USA, 06269.
Adv Mater. 2013 Nov 20;25(43):6256-60. doi: 10.1002/adma.201302729. Epub 2013 Aug 23.
Diffusion of two monomers and their oxidative copolymerization inside a solid-state gel electrolyte is utilized as a method to match the monomer feed ratio to a color resulting from a conjugated copolymer having a single absorption in the visible region. Here, a combination of two monomers is used to generate a solid-state electrochromic device of any color, except black and green, in the colored state with all other colors going to transmissive sky blue in the bleached state.
利用两种单体在固态凝胶电解质中的扩散及其氧化共聚,将单体进料比与具有单一可见光吸收的共轭共聚物的颜色相匹配。在这里,两种单体的组合用于在有色状态下生成任何颜色的固态电致变色器件,除了黑色和绿色,而在漂白状态下所有其他颜色都变为透明的天蓝色。