• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

链状聚[[双-(2-氯-吡嗪-κN(4))镉]-二-μ-硫氰酸根合-κ(2)N:S;κ(2)S:N]

catena-Poly[[bis-(2-chloro-pyrazine-κN (4))cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].

作者信息

Wöhlert Susanne, Jess Inke, Näther Christian

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 9;69(Pt 4):m195. doi: 10.1107/S1600536813006338. Print 2013 Apr 1.

DOI:10.1107/S1600536813006338
PMID:23633995
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3629477/
Abstract

Reaction of cadmium thio-cyanate with 2-chloro-pyrazine leads to the polymeric title compound, [Cd(NCS)2(C4H3ClN2)2] n . The Cd(II) cation, which is located on a center of inversion, is coordinated by two N-bonded and two S-bonded thio-cyanate anions and by two N-bonded 2-chloro-pyrazine ligands within a slightly distorted octa-hedron. The Cd(II) cations are linked into chains along the a axis by bridging thio-cyanate anions.

摘要

硫氰酸镉与2-氯吡嗪反应生成聚合标题化合物[Cd(NCS)₂(C₄H₃ClN₂)₂]ₙ。位于对称中心的Cd(II)阳离子，在一个轻微扭曲的八面体中，由两个通过N键合和两个通过S键合的硫氰酸根阴离子以及两个通过N键合的2-氯吡嗪配体配位。Cd(II)阳离子通过桥连硫氰酸根阴离子沿a轴连接成链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6e6/3629477/16962b2889f9/e-69-0m195-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6e6/3629477/7220bb72a106/e-69-0m195-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6e6/3629477/16962b2889f9/e-69-0m195-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6e6/3629477/7220bb72a106/e-69-0m195-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6e6/3629477/16962b2889f9/e-69-0m195-fig2.jpg

相似文献

1
catena-Poly[[bis-(2-chloro-pyrazine-κN (4))cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].链状聚[[双-(2-氯-吡嗪-κN(4))镉]-二-μ-硫氰酸根合-κ(2)N:S;κ(2)S:N]
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 9;69(Pt 4):m195. doi: 10.1107/S1600536813006338. Print 2013 Apr 1.
2
Syntheses and crystal structures of bis-(4-methyl-pyridine-κ)bis-(seleno-cyanato-κ)zinc(II) and -poly[[bis-(4-methyl-pyridine-κ)cadmium(II)]-di-μ-seleno-cyanato-κ :;κ :].双（4-甲基吡啶-κ）双（硒氰酸根合-κ）锌（II）和聚[[双（4-甲基吡啶-κ）镉（II）]-二-μ-硒氰酸根合-κ:;κ:]的合成与晶体结构
Acta Crystallogr E Crystallogr Commun. 2023 Feb 7;79(Pt 3):136-141. doi: 10.1107/S2056989023000920. eCollection 2023 Feb 1.
3
catena-Poly[[bis-(thio-cyanato-κN)iron(II)]-bis-(μ-dipyrazin-2-yl di-sulfide-κ(2) N (4):N (4'))].链状聚[[双（硫氰酸根合-κN）铁（II）]-双（μ-二吡嗪-2-基二硫化物-κ(2) N (4):N (4')]
Acta Crystallogr Sect E Struct Rep Online. 2013 Aug 10;69(Pt 9):m487. doi: 10.1107/S1600536813021958. eCollection 2013.
4
Crystal structure of catena-poly[[(3-tert-butyl-pyridine-κN)(4-tert-butyl-pyridine-κN)cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].链状聚[[(3-叔丁基吡啶-κN)(4-叔丁基吡啶-κN)镉]-二-μ-硫氰酸根合-κ(2)N:S;κ(2)S:N]的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Nov 19;70(Pt 12):m403-4. doi: 10.1107/S1600536814024647. eCollection 2014 Dec 1.
5
catena-Poly[(E)-4,4'-(ethene-1,2-di-yl)dipyridinium [[bis-(thio-cyanato-κN)ferrate(II)]-di-μ-thio-cyanato-κN:S;κS:N]].链状聚[（E）-4,4'-（乙烯-1,2-二基）二吡啶鎓[[双（硫氰酸根-κN）铁（II）]-二-μ-硫氰酸根-κN:S；κS:N]]
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 15;66(Pt 10):m1256. doi: 10.1107/S160053681003624X.
6
catena-Poly[[bis-[2-(1H-1,2,4-triazol-1-yl-κN)pyrazine]cadmium(II)]-di-μ-thio-cyanato-κS:N;κN:S].链状聚[[双-[2-(1H-1,2,4-三唑-1-基-κN)吡嗪]镉(II)]-二-μ-硫氰酸根合-κS:N;κN:S]
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):m935. doi: 10.1107/S1600536809027135.
7
catena-Poly[[bis-(pyridine-κN)nickel(II)]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].链状聚[[双（吡啶-κN）镍（II）]-二-μ-硫氰酸根-κ(2) N:S;κ(2) S:N]
Acta Crystallogr Sect E Struct Rep Online. 2014 May 3;70(Pt 6):m196. doi: 10.1107/S1600536814009611. eCollection 2014 Jun 1.
8
catena-Poly[[bis-(3-acetyl-pyridine-κN)cadmium]-di-μ-seleno-cyanato-κ(2)N:Se;κ(2)Se:N].链状聚[[双-(3-乙酰基吡啶-κN)镉]-二-μ-硒氰酸根-κ(2)N:Se;κ(2)Se:N]
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m704. doi: 10.1107/S1600536812018375. Epub 2012 Apr 28.
9
catena-Poly[(E)-4,4'-(ethane-1,2-di-yl)dipyridinium [[bis-(thio-cyanato-κN)ferrate(II)]-di-μ-thio-cyanato-κN:S;κS:N]].链状聚[（E）-4,4'-（乙烷-1,2-二基）二吡啶鎓[[双（硫氰酸根-κN）铁（II）]-二-μ-硫氰酸根-κN:S;κS:N]]
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1503. doi: 10.1107/S1600536811039924. Epub 2011 Oct 8.
10
Poly[(aceto-nitrile-κN)-μ3-thio-cyanato-κ(3) N:S:S-μ2-thio-cyanato-κ(2) N:S-cadmium].聚[（乙腈-κN）-μ3-硫氰酸根合-κ(3)N:S:S-μ2-硫氰酸根合-κ(2)N:S-镉]
Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 15;69(Pt 7):m398. doi: 10.1107/S1600536813015870. eCollection 2013.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.