• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双{1-[(E)-(2-氯苯基)重氮基]萘-2-醇根合}铜(II)

Bis{1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olato}copper(II).

作者信息

Benaouida Mohamed Amine, Benosmane Ali, Bouguerria Hassiba, Bouaoud Salah Eddine, Merazig Hocine

机构信息

Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1, Algeria.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 22;69(Pt 7):m405. doi: 10.1107/S1600536813016681. eCollection 2013.

DOI:10.1107/S1600536813016681
PMID:24046576
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3772433/
Abstract

The Cu(II) atom in the title compound, [Cu(C16H10ClN2O)2], is located on an inversion center and is tetra-coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol-ecules are linked via weak C-H⋯O and C-H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π-π inter-actions present involving adjacent naphthalene rings [centroid-centroid distance = 3.661 (13) Å].

摘要

标题化合物[Cu(C₁₆H₁₀ClN₂O)₂]中的铜(II)原子位于一个对称中心上，由来自两个双齿1-[(E)-(2-氯苯基)重氮基]萘-2-醇配体的两个氮原子和两个氧原子进行四配位，形成一个平面正方形配合物。在晶体中，分子通过弱的C-H⋯O和C-H⋯Cl氢键相连，形成沿[010]方向延伸的链。还存在涉及相邻萘环的π-π相互作用[质心-质心距离 = 3.661 (13) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fc1/3772433/d6277187f4ef/e-69-0m405-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fc1/3772433/35cfc6241170/e-69-0m405-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fc1/3772433/d6277187f4ef/e-69-0m405-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fc1/3772433/35cfc6241170/e-69-0m405-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8fc1/3772433/d6277187f4ef/e-69-0m405-fig2.jpg

相似文献

1
Bis{1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olato}copper(II).双{1-[(E)-(2-氯苯基)重氮基]萘-2-醇根合}铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 22;69(Pt 7):m405. doi: 10.1107/S1600536813016681. eCollection 2013.
2
Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-ol.配体（E）-1-[(2,4,6-三溴苯基)重氮基]萘-2-醇的铜（II）以及同型镍（II）和钯（II）配合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Jul 12;72(Pt 8):1093-8. doi: 10.1107/S205698901601080X. eCollection 2016 Aug 1.
3
Crystal structure, characterization and Hirshfeld analysis of bis-{()-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-olato}copper(II) dimethyl sulfoxide monosolvate.双-{()-1-[(2,4,6-三溴苯基)重氮基]萘-2-醇酸根合}铜(II)二甲基亚砜单溶剂化物的晶体结构、表征及 Hirshfeld 分析
Acta Crystallogr E Crystallogr Commun. 2020 Feb 18;76(Pt 3):382-386. doi: 10.1107/S2056989020001863. eCollection 2020 Mar 1.
4
Crystal structure of bis-{μ-1-[(E)-(3-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olato-κ(3) N (2),O:O}bis-({1-[(E)-(3-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olato-κ(2) N (2),O}copper(II)).双-{μ-1-[(E)-(3-甲氧基苯基)重氮基]萘-2-醇根合-κ(3) N(2),O:O}双({1-[(E)-(3-甲氧基苯基)重氮基]萘-2-醇根合-κ(2) N(2),O}铜(II))的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Nov 7;71(Pt 12):m211-2. doi: 10.1107/S2056989015020824. eCollection 2015 Dec 1.
5
(E)-1-[2-(2-Cyano-phen-yl)diazen-2-ium-1-yl]naphthalen-2-olate.（E）-1-[2-（2-氰基苯基）重氮-2-鎓-1-基]萘-2-醇盐
Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 29;69(Pt 7):o1175-6. doi: 10.1107/S1600536813017261. eCollection 2013.
6
Crystal structure of bis-{1-[(E)-(2-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olato-κ(3) O,N (2),O'}copper(II) containing an unknown solvate.含有未知溶剂化物的双-{1-[(E)-(2-甲氧基苯基)重氮基]萘-2-醇根-κ(3) O,N(2),O'}铜(II)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Oct 31;71(Pt 11):m207-8. doi: 10.1107/S2056989015019817. eCollection 2015 Nov 1.
7
1-[(E)-2-(2-Hy-droxy-5-methyl-phen-yl)diazen-2-ium-1-yl]naphthalen-2-olate.1-[(E)-2-(2-羟基-5-甲基苯基)重氮-2-鎓-1-基]萘-2-酚盐
Acta Crystallogr Sect E Struct Rep Online. 2013 Jul 27;69(Pt 8):o1322-3. doi: 10.1107/S160053681302014X. eCollection 2013.
8
1-(4-Hy-droxy-phen-yl)-2-(2-oxidonaphthalen-1-yl)diazen-1-ium methanol hemisolvate.1-（4-羟基苯基）-2-（2-氧化萘-1-基）重氮-1-鎓甲醇半溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2013 May 11;69(Pt 6):o867-8. doi: 10.1107/S1600536813012245. Print 2013 Jun 1.
9
(E)-1-[(2-Amino-5-nitro-phen-yl)iminio-meth-yl]naphthalen-2-olate.（E）-1- [（2-氨基-5-硝基-苯基）亚氨基甲基]萘-2-醇盐
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 30;66(Pt 5):o1227-8. doi: 10.1107/S1600536810014923.
10
Crystal structure of bis-[μ-meth-oxy(pyridin-2-yl)methano-lato-κ(3) N,O:O]bis[chlorido-copper(II)].双[μ-甲氧基（吡啶-2-基）甲醇根-κ(3) N,O:O]双[氯合铜（II）]的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jan 31;71(Pt 2):m44-5. doi: 10.1107/S2056989015001310. eCollection 2015 Feb 1.

引用本文的文献

1
Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-ol.配体（E）-1-[(2,4,6-三溴苯基)重氮基]萘-2-醇的铜（II）以及同型镍（II）和钯（II）配合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Jul 12;72(Pt 8):1093-8. doi: 10.1107/S205698901601080X. eCollection 2016 Aug 1.

本文引用的文献

1
Bis{1-[(E)-(2-methyl-phen-yl)diazen-yl]-2-naphtho-lato}palladium(II).双{1-[(E)-(2-甲基苯基)重氮基]-2-萘酚根合}钯(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 24;66(Pt 8):m1022. doi: 10.1107/S1600536810028916.
2
Bis{1-[(E)-o-tolyl-diazen-yl]-2-naphtho-l-ato}copper(II).
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):m1315. doi: 10.1107/S1600536810037888.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
4
Regioselective complexation of metal ion in chromogenic calix[4]biscrowns.生色杯[4]双冠醚中金属离子的区域选择性络合作用
J Org Chem. 2004 Apr 16;69(8):2902-5. doi: 10.1021/jo049954o.