SPSMS, UMR-E 9001, CEA-INAC/UJF-Grenoble 1, 17 rue des martyrs, 38054 Grenoble Cedex 9, France.
Nanoscale. 2013 Nov 21;5(22):10996-1002. doi: 10.1039/c3nr02934d. Epub 2013 Sep 25.
Metal-graphene interfaces generated by electrode deposition induce barriers or potential modulations influencing the electronic transport properties of graphene based devices. However, their impact on the local mechanical properties of graphene is much less studied. Here we show that graphene near a metallic interface can exhibit a set of ripples self-organized into domains whose topographic roughness is controlled by the tip bias of a scanning tunneling microscope. The reconstruction from topographic images of graphene bending energy maps sheds light on the local electro-mechanical response of graphene under STM imaging and unveils the role of the stress induced by the vicinity of the graphene-metal interface in the formation and the manipulation of these ripples. Since microscopic rippling is one of the important factors that limit charge carrier mobility in graphene, the control of rippling with a gate voltage may have important consequences in the conductance of graphene devices where transverse electric fields are created by contactless suspended gate electrodes. This opens up also the possibility to dynamically control the local morphology of graphene nanomembranes.
金属-石墨烯界面通过电极沉积产生,会诱导势垒或电位调制,从而影响基于石墨烯的器件的电子输运特性。然而,它们对石墨烯局部力学性能的影响却研究得很少。在这里,我们表明,在金属界面附近的石墨烯可以表现出一组波纹,这些波纹自组织成畴,其地形粗糙度由扫描隧道显微镜的针尖偏置控制。从石墨烯弯曲能量图的地形图像重建揭示了在 STM 成像下石墨烯的局部机电响应,并揭示了由石墨烯-金属界面附近的应力引起的在这些波纹的形成和操纵中的作用。由于微观波纹是限制石墨烯中载流子迁移率的重要因素之一,因此通过栅极电压控制波纹可能会对通过无接触悬浮栅电极产生横向电场的石墨烯器件的电导率产生重要影响。这也为动态控制石墨烯纳米膜的局部形态开辟了可能性。