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具有琼脂糖凝胶的混合 MnO2 薄膜,用于增强薄膜超级电容器电极的结构完整性。

Hybrid MnO2 film with agarose gel for enhancing the structural integrity of thin film supercapacitor electrodes.

机构信息

World Class University (WCU) program of Chemical Convergence for Energy & Environment (C2E2), Institute of Chemical Processes, School of Chemical and Biological Engineering, College of Engineering, Seoul National University , Seoul, 151-742, Republic of Korea.

出版信息

ACS Appl Mater Interfaces. 2013 Oct 23;5(20):9908-12. doi: 10.1021/am403532m. Epub 2013 Oct 3.

DOI:10.1021/am403532m
PMID:24080145
Abstract

We report on the fabrication of a robust hybrid film containing MnO2 for achieving large areal capacitances. An agarose gel, as an ion-permeable and elastic layer coated on a current collector, plays a key role in stabilizing the deposited pseudocapacitive MnO2. Cyclic voltammetry and electrochemical impedance spectroscopy data indicate that the hybrid electrode is capable of exhibiting a high areal capacitance up to 52.55 mF cm(-2), with its superior structural integrity and adhesiveness to the current collector being maintained, even at a high MnO2 loading.

摘要

我们报告了一种稳健的混合薄膜的制备,其中包含 MnO2 以实现大的面电容。琼脂糖凝胶作为涂覆在集流器上的离子可渗透和弹性层,在稳定沉积的赝电容 MnO2 方面起着关键作用。循环伏安法和电化学阻抗谱数据表明,即使在高 MnO2 负载下,该混合电极也能够表现出高达 52.55 mF cm(-2) 的高面电容,同时保持其对集流器的优异结构完整性和粘附性。

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