Graduate School of EEWS, ‡Department of Mechanical Engineering, §Department of Materials Science and Engineering and ∥KAIST Institute NanoCentury, Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 305-701, Republic of Korea.
Nano Lett. 2013;13(11):5753-61. doi: 10.1021/nl403860k. Epub 2013 Nov 4.
Wearable electronics represent a significant paradigm shift in consumer electronics since they eliminate the necessity for separate carriage of devices. In particular, integration of flexible electronic devices with clothes, glasses, watches, and skin will bring new opportunities beyond what can be imagined by current inflexible counterparts. Although considerable progresses have been seen for wearable electronics, lithium rechargeable batteries, the power sources of the devices, do not keep pace with such progresses due to tenuous mechanical stabilities, causing them to remain as the limiting elements in the entire technology. Herein, we revisit the key components of the battery (current collector, binder, and separator) and replace them with the materials that support robust mechanical endurance of the battery. The final full-cells in the forms of clothes and watchstraps exhibited comparable electrochemical performance to those of conventional metal foil-based cells even under severe folding-unfolding motions simulating actual wearing conditions. Furthermore, the wearable textile battery was integrated with flexible and lightweight solar cells on the battery pouch to enable convenient solar-charging capabilities.
可穿戴电子设备代表了消费电子产品的重大范式转变,因为它们消除了对设备单独携带的需求。特别是,将柔性电子设备与衣服、眼镜、手表和皮肤集成,将为当前非柔性同类产品无法想象的领域带来新的机会。尽管可穿戴电子产品取得了相当大的进展,但由于机械稳定性脆弱,作为设备的电源,锂离子可充电电池并没有跟上这一进展,这使得它们仍然是整个技术的限制因素。在此,我们重新审视电池的关键组件(集流器、粘合剂和隔膜),并用支持电池强大机械耐久性的材料替代它们。最终,以衣服和表带形式呈现的全电池在经受严重的折叠-展开运动(模拟实际佩戴条件)时,表现出与传统金属箔基电池相当的电化学性能。此外,可穿戴纺织电池与电池袋上的柔性和轻量级太阳能电池集成,实现了便捷的太阳能充电功能。