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新型 Ag(2)O/Ag(2)CO(3) 异质结构的相变合成及其在光催化降解污染物中的可见光高效性。

Phase transformation synthesis of novel Ag(2)O/Ag(2)CO(3) heterostructures with high visible light efficiency in photocatalytic degradation of pollutants.

机构信息

School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, 86 Hongqi Road, Ganzhou, 341000, Jiangxi, China; Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania, 15213, USA.

出版信息

Adv Mater. 2014 Feb 12;26(6):892-8. doi: 10.1002/adma.201304173. Epub 2013 Oct 27.

Abstract

Coreshell-like Ag2 O/Ag2 CO3 nanoheterostructures with tailored interface are fabricated by a facile, low-cost and one-step phase transformation method. The unique bandgap structure of the Ag2 O/Ag2 CO3 exhibits high separation efficiency of photogenerated electrons and holes, which effectively protects the Ag2 CO3 semiconductor to avoid its photoreduction and gives rise to high activity and stability in degradation of the typical water pollutants.

摘要

核壳状 Ag2 O/Ag2 CO3 纳米异质结构具有定制的界面,通过简便、低成本的一步相变法制备。Ag2 O/Ag2 CO3 的独特能带结构表现出光生电子和空穴的高效分离效率,有效保护了 Ag2 CO3 半导体以避免光还原,并在降解典型水污染物方面表现出高活性和稳定性。

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