[刺果飞廉全草的化学成分]
[Chemical constituents from whole plants of Carduus acanthoides].
作者信息
Liu Sui-Ku, Que Sheng, Cheng Wei, Zhang Qing-Ying, Liang Hong
机构信息
State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Beijing 100191, China.
出版信息
Zhongguo Zhong Yao Za Zhi. 2013 Jul;38(14):2334-7.
Fourteen compounds were isolated from wholeplants of Carduus acanthoides by various chromatographic techniques including column chromatography over HP-20 macroporous resin, MCI gel, silica gel, Sephadex LH-20 and ODS and reversed-phase HPLC. Their structures were identified as salidroside (1), 2-(3,4-dihydroxyphenyl)-ethyl-O-beta-D-glucopyranoside (2), 3,5-di-hydroxyphenethyl alcohol-3-O-beta-D-glucopyranoside (3), p-coumaric acid (4), 3-hydroxy-1-(4-hydroxy-3-methoxyphenyl) propan-1-one (5), 3-hydroxy-1-(4-hydroxy-3,5-dimethoxyphenyl) propan-1-one (6), syringin (7), p-hydroxybenzaldehyde (8), salicylic acid (9), tachioside (10), vanillic acid-4-O-beta-D-glucopyranoside (11), syringic aldehyde (12), 2,6-dimethoxy-4-hydroxyphenol-1-O-beta-D-glucopyranoside (13), and 2, 6-dimethoxy-p-hydroquinone-4-0-P-D-glucopyranoside (14) on the basis of spectroscopic data analysiS. All compounds were isolated from the genus Carduus for the first time except for compounds 4 and 7.
通过多种色谱技术，包括在HP - 20大孔树脂、MCI凝胶、硅胶、Sephadex LH - 20和ODS上的柱色谱以及反相高效液相色谱，从刺苞飞廉全草中分离出了14种化合物。基于光谱数据分析，它们的结构被鉴定为红景天苷（1）、2 -（3,4 - 二羟基苯基） - 乙基 - O - β - D - 吡喃葡萄糖苷（2）、3,5 - 二羟基苯乙醇 - 3 - O - β - D - 吡喃葡萄糖苷（3）、对香豆酸（4）、3 - 羟基 - 1 -（4 - 羟基 - 3 - 甲氧基苯基）丙 - 1 - 酮（5）、3 - 羟基 - 1 -（4 - 羟基 - 3,5 - 二甲氧基苯基）丙 - 1 - 酮（6）、紫丁香苷（7）、对羟基苯甲醛（8）、水杨酸（9）、紫堇苷（10）、香草酸 - 4 - O - β - D - 吡喃葡萄糖苷（11）、丁香醛（12）、2,6 - 二甲氧基 - 4 - 羟基苯酚 - 1 - O - β - D - 吡喃葡萄糖苷（13）和2,6 - 二甲氧基 - 对苯二酚 - 4 - O - β - D - 吡喃葡萄糖苷（14）。除化合物4和7外，所有化合物均为首次从飞廉属植物中分离得到。
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