纳米颗粒中的磁性:通过涂层调节性能。

Magnetism in nanoparticles: tuning properties with coatings.

作者信息

Crespo Patricia, de la Presa Patricia, Marín Pilar, Multigner Marta, Alonso José María, Rivero Guillermo, Yndurain Félix, González-Calbet José María, Hernando Antonio

出版信息

J Phys Condens Matter. 2013 Dec 4;25(48):484006. doi: 10.1088/0953-8984/25/48/484006.

Abstract

This paper reviews the effect of organic and inorganic coatings on magnetic nanoparticles. The ferromagnetic-like behaviour observed in nanoparticles constituted by materials which are non-magnetic in bulk is analysed for two cases: (a) Pd and Pt nanoparticles, formed by substances close to the onset of ferromagnetism, and (b) Au and ZnO nanoparticles, which were found to be surprisingly magnetic at the nanoscale when coated by organic surfactants. An overview of theories accounting for this unexpected magnetism, induced by the nanosize influence, is presented. In addition, the effect of coating magnetic nanoparticles with biocompatible metals, oxides or organic molecules is also reviewed, focusing on their applications.

摘要

本文综述了有机和无机涂层对磁性纳米粒子的影响。分析了由体相中为非磁性材料构成的纳米粒子中观察到的类铁磁行为的两种情况:(a) 由接近铁磁性起始点的物质形成的钯和铂纳米粒子,以及 (b) 金和氧化锌纳米粒子,它们在被有机表面活性剂包覆时在纳米尺度上表现出令人惊讶的磁性。概述了由纳米尺寸影响引起的这种意外磁性的相关理论。此外,还综述了用生物相容性金属、氧化物或有机分子包覆磁性纳米粒子的效果,重点介绍了它们的应用。

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