• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

在四极离子阱质谱仪上采用内部脉冲阀进样。

Internal pulsed valve sample introduction on a quadrupole ion trap mass spectrometer.

机构信息

Department of Chemistry, University of Florida, Gainesville, Florida, USA.

出版信息

J Am Soc Mass Spectrom. 1995 Oct;6(10):976-80. doi: 10.1016/1044-0305(95)00528-L.

DOI:10.1016/1044-0305(95)00528-L
PMID:24214042
Abstract

A pulsed valve positioned just outside the ion trap electrodes (within the vacuum chamber) has been characterized. The observed gas pulse widths and the maximum ion intensities were found to decrease as the distance between the pulsed valve and the ion trap electrodes increased. An explanation is presented within. The pulsed valve was found to impart temporal separation in ion-molecule reactions by permitting the removal of interfering neutrals. Other factors that affect the degree of temporal separation also are presented.

摘要

一个位于离子阱电极(在真空室内)外部的脉冲阀已经过了特性描述。观察到的气体脉冲宽度和最大离子强度随着脉冲阀和离子阱电极之间的距离增加而减小。在本文中给出了一个解释。脉冲阀通过允许去除干扰中性粒子,从而在离子-分子反应中引入时间分离。还提出了其他影响时间分离程度的因素。

相似文献

1
Internal pulsed valve sample introduction on a quadrupole ion trap mass spectrometer.在四极离子阱质谱仪上采用内部脉冲阀进样。
J Am Soc Mass Spectrom. 1995 Oct;6(10):976-80. doi: 10.1016/1044-0305(95)00528-L.
2
Coupling of ion-molecule reactions with liquid chromatography on a quadrupole ion trap mass spectrometer.四极杆离子阱质谱仪上离子 - 分子反应与液相色谱的联用
Rapid Commun Mass Spectrom. 2008 Apr;22(8):1288-94. doi: 10.1002/rcm.3494.
3
Integration of a Multichannel Pulsed-Valve Inlet System to a Linear Quadrupole Ion Trap Mass Spectrometer for the Rapid Consecutive Introduction of Nine Reagents for Diagnostic Ion/Molecule Reactions.将多通道脉冲阀进气系统集成到线性四极离子阱质谱仪中,用于快速连续引入用于诊断离子/分子反应的九种试剂。
Anal Chem. 2019 Dec 17;91(24):15652-15660. doi: 10.1021/acs.analchem.9b03768. Epub 2019 Nov 21.
4
Multiported pulsed valve interface for a linear quadrupole ion trap mass spectrometer to enable rapid screening of multiple functional-group selective ion-molecule reactions.用于线性四极离子阱质谱仪的多端口脉冲阀接口,可实现多种官能团选择的离子-分子反应的快速筛选。
Anal Chem. 2014 Jul 1;86(13):6533-9. doi: 10.1021/ac501034v. Epub 2014 Jun 19.
5
Pulsed helium introduction into a quadrupole ion trap for reduced collisional quenching during infrared multiphoton dissociation of electrosprayed ions.在电喷雾离子的红外多光子解离过程中,将脉冲氦气引入四极离子阱以减少碰撞猝灭。
Rapid Commun Mass Spectrom. 2000;14(15):1391-7. doi: 10.1002/1097-0231(20000815)14:15<1391::AID-RCM36>3.0.CO;2-O.
6
Pulsed gas introduction into quadrupole ion traps.脉冲气体导入四极离子阱。
J Am Soc Mass Spectrom. 1990 Jul;1(4):308-11. doi: 10.1016/1044-0305(90)85006-8.
7
A pulsed-leak valve for use with ion trapping mass spectrometers.一种用于离子阱质谱仪的脉冲泄漏阀。
J Am Soc Mass Spectrom. 1996 Jan;7(1):118-22. doi: 10.1016/1044-0305(95)00674-5.
8
Direct Analysis of Organic Compounds in Liquid Using a Miniature Photoionization Ion Trap Mass Spectrometer with Pulsed Carrier-Gas Capillary Inlet.使用带有脉冲载气毛细管入口的微型光离子化离子阱质谱仪直接分析液体中的有机化合物。
J Am Soc Mass Spectrom. 2017 Aug;28(8):1702-1708. doi: 10.1007/s13361-017-1683-2. Epub 2017 Apr 21.
9
Gas phase hydrogen/deuterium exchange reactions of peptide ions in a quadrupole ion trap mass spectrometer.
Proteins. 1997 May;28(1):53-8.
10
Pulsed ion extraction diagnostics in a quadrupole ion trap linear time-of-flight mass spectrometer.四极杆离子阱线性飞行时间质谱仪中的脉冲离子提取诊断技术。
Rev Sci Instrum. 2010 Jun;81(6):063302. doi: 10.1063/1.3436659.

引用本文的文献

1
MS/MS of ions in a low pressure linear ion trap using a pulsed gas.使用脉冲气体在低压线性离子阱中进行离子的串联质谱分析。
J Am Soc Mass Spectrom. 2009 Sep;20(9):1714-7. doi: 10.1016/j.jasms.2009.05.005. Epub 2009 May 20.

本文引用的文献

1
Pulsed gas introduction into quadrupole ion traps.脉冲气体导入四极离子阱。
J Am Soc Mass Spectrom. 1990 Jul;1(4):308-11. doi: 10.1016/1044-0305(90)85006-8.
2
Estimation of mutagenic/carcinogenic potential of environmental contaminants by ion-molecule reactions and tandem mass spectrometry.通过离子-分子反应和串联质谱法评估环境污染物的致突变/致癌潜力。
J Am Soc Mass Spectrom. 1990 Feb;1(1):110-5. doi: 10.1016/1044-0305(90)80014-E.
3
Alternating RF/DC Isolations for Quantitation with Coeluting Internal Standards in Gas Chromatography/Ion Trap Mass Spectrometry.
气相色谱/离子阱质谱联用中同流路内标法定量的交变频 RF/DC 隔离技术。
J Am Soc Mass Spectrom. 1992 Jan;3(1):85-8. doi: 10.1016/1044-0305(92)85022-C.
4
Information on the location of carbon-carbon double bonds in C6-C 23 linear alkenes from carbon addition reactions in a quadrupole ion trap equipped with a pulsed sample-inlet system.在配备脉冲进样系统的四极离子阱中,通过碳加成反应得到 C6-C23 直链烯中碳-碳双键位置的信息。
J Am Soc Mass Spectrom. 1991 Aug;2(4):305-13. doi: 10.1016/1044-0305(91)80022-Y.
5
Selective detection of the tolyl cation among other [C7H 7] (+) isomers by ion/molecule reaction with dimethyl ether.通过与二甲醚的离子/分子反应,选择性地检测其他 [C7H 7] (+) 异构体中的甲苯阳离子。
J Am Soc Mass Spectrom. 1991 Aug;2(4):270-7. doi: 10.1016/1044-0305(91)80018-3.
6
Functional group-selective ion-molecule reactions of ethylene glycol and its monomethyl and dimethyl ethers.乙二醇及其单甲基和二甲基醚的功能基团选择性离子-分子反应。
J Am Soc Mass Spectrom. 1993 Feb;4(2):97-105. doi: 10.1016/1044-0305(93)85064-5.
7
Fourier-transform electrospray instrumentation for tandem high-resolution mass spectrometry of large molecules.傅里叶变换电喷雾仪器用于大型分子的串联高分辨率质谱分析。
J Am Soc Mass Spectrom. 1993 Jul;4(7):557-65. doi: 10.1016/1044-0305(93)85017-R.
8
Gas-phase ion-molecule reactions: a model for the determination of biologically reactive electrophilic contaminants in the environment.气相离子-分子反应:一种用于测定环境中具有生物活性的亲电污染物的模型。
Anal Chem. 1994 Jun 1;66(11):1902-10. doi: 10.1021/ac00083a021.