Center for Catalytic Hydrocarbon Functionalizations (IBS), Daejeon 305-701, Korea.
Chem Commun (Camb). 2014 Jan 14;50(4):448-50. doi: 10.1039/c3cc47926a.
Cu(II)-catalyzed cyanation of aryl iodides has been developed using DMF and ammonium bicarbonate as the combined source of cyanide. It is assumed that copper is involved both in the generation of "CN" units from DMF-ammonia and in the cyanation of aryl halides. A range of electron-rich and fused (hetero)aryl iodides underwent cyanation resulting in moderate to good yields.
开发了一种使用 DMF 和碳酸氢铵作为氰化物的组合来源的 Cu(II)催化芳基碘化物的氰化反应。假设铜既参与了 DMF-氨中“CN”单元的生成，也参与了芳基卤化物的氰化反应。一系列富电子和稠合（杂）芳基碘化物进行了氰化反应，得到了中等至良好的产率。
