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超越溶剂:二甲基甲酰胺在有机化学中的三重作用

Beyond a solvent: triple roles of dimethylformamide in organic chemistry.

作者信息

Heravi Majid M, Ghavidel Mahdieh, Mohammadkhani Leyla

机构信息

Department of Chemistry, School of Sciences, Alzahra University Vanak Tehran Iran

出版信息

RSC Adv. 2018 Aug 3;8(49):27832-27862. doi: 10.1039/c8ra04985h. eCollection 2018 Aug 2.

Abstract

,-Dimethylformamide (DMF) is frequently used as an aprotic solvent in chemical transformations in laboratories of academia as well as in those of chemical industry. In the present review, we will reveal that DMF is actually something much more than a solvent. It is a unique chemical since, as well as being an effective polar aprotic solvent, it can play three other important roles in organic chemistry. It can be used as a reagent, a catalyst, and a stabilizer.

摘要

N,N-二甲基甲酰胺(DMF)在学术界和化工行业的实验室中经常被用作非质子溶剂用于化学转化。在本综述中,我们将揭示DMF实际上远不止是一种溶剂。它是一种独特的化学品,因为除了是一种有效的极性非质子溶剂外,它在有机化学中还可以发挥其他三个重要作用。它可以用作试剂、催化剂和稳定剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a3e/9084326/ae8a376483a0/c8ra04985h-f1.jpg

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