School of Applied Sciences, University of Science and Technology Beijing, Beijing, China.
J Air Waste Manag Assoc. 2013 Oct;63(10):1173-81. doi: 10.1080/10962247.2013.807318.
Gas chromatography-mass spectrometry, olfactometry, and other related methods were applied for the qualitative and quantitative analysis of the characteristics of odorous gases in the pretreatment workshop. The composition of odorous gases emitted from municipal food waste was also investigated in this study. The results showed that the tested gases are mainly composed of aromatic gases, which account for 49% of the total volatile organic compounds (VOC) concentrations. The nitrogenous compounds comprise 15% of the total concentration and the other gases comprise the remaining 36%. The level of odor concentration ranged from 2523 odor units (OU) m(-3) to 3577 OU m(-3). The variation of the total chemical composition ranged from 19,725 microg m(-3) to 24,184 microg m(-3). Among the selected four sampling points, the discharge outlet was detected to have the highest concentration in terms of odor, total chemical, sulfur compounds, and aromatics. The correlation analysis showed that the odor concentrations were evidently related to the total chemical composition, sulfur compounds, and aromatics (P < 0.05, n = 5). The odor activity value analysis identified the top three compounds, hydrogen sulfide (91.8), ethyl sulfide (35.8), and trimethylamine (70.6), which contribute to air pollution complaint of waste materials.
采用气相色谱-质谱联用、嗅闻法等相关方法对预处理车间恶臭气体的特征进行了定性和定量分析。本研究还考察了城市食品垃圾排放恶臭气体的组成。结果表明,被测气体主要由芳香族气体组成,占总挥发性有机化合物(VOC)浓度的 49%。含氮化合物占总浓度的 15%,其余气体占 36%。恶臭浓度范围为 2523 气味单位(OU)/m³至 3577 OU/m³。总化学成分的变化范围为 19725 微克/m³至 24184 微克/m³。在选择的四个采样点中,出气口在气味、总化学物质、硫化合物和芳烃方面的浓度最高。相关分析表明,气味浓度与总化学成分、硫化合物和芳烃明显相关(P<0.05,n=5)。气味活性值分析确定了三种主要化合物,硫化氢(91.8)、乙硫醇(35.8)和三甲胺(70.6),它们对废物空气污染投诉有贡献。