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鉴定带斑瓜萤叶甲(鞘翅目:叶甲科)雌性分泌的性信息素。

Identification of female-produced sex pheromone from banded cucumber beetle,Diabrotica balteata leconte (Coleoptera: Chrysomelidae).

机构信息

Japan Tobacco Inc., Yokohama, 227, Kanagama, Japan.

出版信息

J Chem Ecol. 1987 Jul;13(7):1601-16. doi: 10.1007/BF00980203.

Abstract

A sex pheromone produced by female banded cucumber beetle adults,Diabrotica balteata LeConte, was isolated from volatiles trapped on Porapak Q and identified as 6,12-dimethylpentadecan-2-one. The structure was elucidated by spectroscopic analyses and confirmed by synthesis. The synthesized racemic compound was equal to the purified natural pheromone in eliciting responses by banded cucumber beetle males to field traps. A doseresponse characteristic was demonstrated for the racemic material formulated on filter paper or rubber septa and placed in field traps. The absolute configuration at the C-6 and C-12 positions was not established.

摘要

由雌性 banded cucumber beetle 成虫产生的性信息素,Diabrotica balteata LeConte,从 Porapak Q 捕获的挥发物中分离出来,并鉴定为 6,12-二甲基十五烷-2-酮。该结构通过光谱分析阐明,并通过合成得到证实。合成的外消旋化合物与纯化的天然信息素一样,能引起 banded cucumber beetle 雄性对田间诱捕器的反应。在滤纸或橡胶隔片上配制的外消旋物质在田间诱捕器中表现出剂量反应特征。C-6 和 C-12 位的绝对构型尚未确定。

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