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向日葵茎象甲表面脂质中的烷烃,Cylindrocopturus adspersus (LeConte)。

Alkanes from surface lipids of sunflower stem weevil,Cylindrocopturus adspersus (LeConte).

机构信息

U.S. Department of Agriculture, Metabolism and Radiation Research Laboratory Agricultural Research Service, 58105, Fargo, North Dakota.

出版信息

J Chem Ecol. 1984 Sep;10(9):1335-47. doi: 10.1007/BF00988115.

DOI:10.1007/BF00988115
PMID:24317585
Abstract

The stem weevil,Cylindrocopturus adspersus (LeConte) (Coleoptera: Curculionidae) yields 3% of its body weight as extractable lipids (40 μg/ weevil). The alkane fraction was composed ofn-alkanes (38%) and branched alkanes (62%). The compounds were characterized by gas chromatography-mass spectrometry (GC-MS). The chromatogram contained several single-component peaks (9 of 25). Only seven dimethylalkanes were isolated (17.8%): 9,19- and 9,21-dimethylheptacosane; 9,19- and 9,21-dimethylnonacosane; 9,21- and 11,21-dimethylhentriacontane; and 11,21-dimethyltritriacontane. Important methylalkanes were: 2-methyltetra- and hexacosanes and 10-methylhexa- and octacosanes. Late-eluting gas chromatography peaks were composed of simple alkane mixtures or a single component.

摘要

茎象甲,Cylindrocopturus adspersus (LeConte)(鞘翅目:象甲科)的可萃取脂质占其体重的 3%(每只象甲 40 μg)。烷烃部分由正构烷烃(38%)和支链烷烃(62%)组成。通过气相色谱-质谱联用仪(GC-MS)对化合物进行了表征。色谱图包含几个单一组分峰(25 个中有 9 个)。仅分离出七种二甲基烷烃(17.8%):9,19-和 9,21-二甲基二十七烷;9,19-和 9,21-二甲基二十九烷;9,21-和 11,21-二甲基三十烷;和 11,21-二甲基三十一烷。重要的甲基烷烃有:2-甲基二十四烷和二十六烷以及 10-甲基二十八烷和三十二烷。迟洗脱的气相色谱峰由简单的烷烃混合物或单一成分组成。

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