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麦克贝恩和胶束的百年纪念。

McBain and the centenary of the micelle.

机构信息

School of Chemistry, University of Bristol, Bristol BS8 1TS, UK.

出版信息

Adv Colloid Interface Sci. 2014 Jan;203:51-4. doi: 10.1016/j.cis.2013.11.012. Epub 2013 Nov 27.

DOI:10.1016/j.cis.2013.11.012
PMID:24345732
Abstract

In 1913, J.W. McBain introduced the word "micelle" into surface and colloid chemistry in the context of the association of surfactant molecules in aqueous solution. This article gives a biographic account of McBain, and reviews the early work on micellar aggregation, leading up to the pioneering ideas of G.S. Hartley who introduced the first model of the spherical micelle that we would recognise today.

摘要

1913 年,J.W.麦克贝恩(J.W. McBain)在表面和胶体化学领域提出了“胶束”一词,用于描述表面活性剂分子在水溶液中的缔合。本文介绍了麦克贝恩的生平和他在胶束聚集方面的早期工作,其中包括 G.S.哈特利(G.S. Hartley)的开创性思想,他引入了我们今天所认识的第一个球形胶束模型。

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McBain and the centenary of the micelle.麦克贝恩和胶束的百年纪念。
Adv Colloid Interface Sci. 2014 Jan;203:51-4. doi: 10.1016/j.cis.2013.11.012. Epub 2013 Nov 27.
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Application of computer simulation free-energy methods to compute the free energy of micellization as a function of micelle composition. 1. Theory.应用计算机模拟自由能方法计算胶束化自由能随胶束组成的变化。1. 理论。
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Mass transport in micellar surfactant solutions: 1. Relaxation of micelle concentration, aggregation number and polydispersity.胶束表面活性剂溶液中的质量传输:1. 胶束浓度、聚集数和多分散性的弛豫
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Fluorescence visualization and modeling of a micelle-free zone formed at the interface between an oil and an aqueous micellar phase during interfacial surfactant transport.在界面活性剂传递过程中,油相与水相胶束之间界面形成的无胶束区的荧光可视化和建模。
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