Departments of Chemistry and Chemical Engineering, Texas A&M University, College Station, Texas, 77842, USA.
Macromol Rapid Commun. 2014 Feb;35(4):437-41. doi: 10.1002/marc.201300845. Epub 2013 Dec 17.
Diblock brush terpolymers (DBTs) with different fluorinated methacrylate-based block segments are synthesized through sequential ring-opening metathesis polymerizations and are used to prepare polymer thin films with predictable film thicknesses. These DBTs exhibit preferable substrate vertical alignments within the films, induced by the relatively lower surface energy of the fluorinated structural components, together with the overall cylindrical morphology of the brush architecture.
嵌段刷三元共聚物（DBTs）具有不同的基于氟甲基丙烯酸酯的嵌段段，通过顺序开环复分解聚合合成，并用于制备具有可预测薄膜厚度的聚合物薄膜。这些 DBTs 在薄膜内表现出更好的基底垂直排列，这是由氟结构成分的相对较低的表面能以及刷状结构的整体圆柱形态共同引起的。
