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δ-氧代-1,1-双(三氟甲基)烷烃的合成及其酸度。

Synthesis of δ-oxo-1,1-bis(triflyl)alkanes and their acidities.

机构信息

School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan.

出版信息

Molecules. 2013 Dec 13;18(12):15531-40. doi: 10.3390/molecules181215531.

DOI:10.3390/molecules181215531
PMID:24352012
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6269671/
Abstract

The reaction of 1,1-bis(triflyl)ethylene generated in situ with enolizable carbonyls yielded δ-oxo-1,1-bis(triflyl)alkane derivatives. Their acidities in both the gas and solution phases were determined.

摘要

1,1-双（三氟甲基）乙烯原位生成的反应与烯醇化羰基化合物生成了δ-氧代-1,1-双（三氟甲基）烷烃衍生物。测定了它们在气相和溶液相中的酸度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/fa949acc698b/molecules-18-15531-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/5a18cbf064eb/molecules-18-15531-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/12642c3a8fee/molecules-18-15531-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/bd27900c6c6a/molecules-18-15531-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/d686586eb864/molecules-18-15531-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/fa949acc698b/molecules-18-15531-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/5a18cbf064eb/molecules-18-15531-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/12642c3a8fee/molecules-18-15531-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/bd27900c6c6a/molecules-18-15531-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/d686586eb864/molecules-18-15531-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d5/6269671/fa949acc698b/molecules-18-15531-g005.jpg

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