δ-氧代-1,1-双(三氟甲基)烷烃的合成及其酸度。
Synthesis of δ-oxo-1,1-bis(triflyl)alkanes and their acidities.
机构信息
School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan.
出版信息
Molecules. 2013 Dec 13;18(12):15531-40. doi: 10.3390/molecules181215531.
Abstract
The reaction of 1,1-bis(triflyl)ethylene generated in situ with enolizable carbonyls yielded δ-oxo-1,1-bis(triflyl)alkane derivatives. Their acidities in both the gas and solution phases were determined.
摘要
1,1-双（三氟甲基）乙烯原位生成的反应与烯醇化羰基化合物生成了δ-氧代-1,1-双（三氟甲基）烷烃衍生物。测定了它们在气相和溶液相中的酸度。
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