铜介导的三氟甲基化反应：三氟甲基甲基磺酸酯与 TMSCF3 在苄基、烯丙基和炔丙基上的反应。
Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3.
机构信息
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China ; College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Lu, Shanghai 201620, China.
出版信息
Beilstein J Org Chem. 2013 Dec 12;9:2862-5. doi: 10.3762/bjoc.9.322. eCollection 2013.
A Cu-mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3 was developed for the first time. This method offers a convenient and economical approach to various trifluoroethyl-containing compounds.
首次发展了一种铜介导的三氟甲基化反应，用于苄基、烯丙基和炔丙基甲烷磺酸盐与 TMSCF3 的反应。该方法为各种含三氟乙基的化合物提供了一种方便和经济的方法。
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