Department of Mathematics and Statistics, York University, , 4700 Keele St., Toronto, Ontario, Canada M3J 1P3.
Philos Trans A Math Phys Eng Sci. 2013 Dec 30;372(2008):20120032. doi: 10.1098/rsta.2012.0032. Print 2014 Feb 13.
Between the study of small finite frameworks and infinite incidentally periodic frameworks, we find the real materials which are large, but finite, fragments that fit into the infinite periodic frameworks. To understand these materials, we seek insights from both (i) their analysis as large frameworks with associated geometric and combinatorial properties (including the geometric repetitions) and (ii) embedding them into appropriate infinite periodic structures with motions that may break the periodic structure. A review of real materials identifies a number of examples with a local appearance of 'unit cells' which repeat under isometries but perhaps in unusual forms. These examples also refocus attention on several new classes of infinite 'periodic' frameworks: (i) columns--three-dimensional structures generated with one repeating isometry and (ii) slabs--three-dimensional structures with two independent repeating translations. With this larger vision of structures to be studied, we find some patterns and partial results that suggest new conjectures as well as many additional open questions. These invite a search for new examples and additional theorems.
在小分子有限框架和无限偶然周期性框架的研究之间,我们找到了实际的材料,这些材料是大的,但有限的,适合无限周期性框架的片段。为了理解这些材料,我们从(i)它们作为具有相关几何和组合性质的大框架的分析(包括几何重复)以及(ii)将它们嵌入具有可能破坏周期性结构的运动的适当无限周期性结构中寻求见解。对实际材料的回顾确定了许多具有局部“单位晶胞”外观的例子,这些例子在等变形下重复,但形式可能不寻常。这些例子还重新关注了几类新的无限“周期性”框架:(i)柱——由一个重复等变形生成的三维结构,以及(ii)板——具有两个独立重复平移的三维结构。通过对要研究的结构有了更广阔的视野,我们发现了一些模式和部分结果,这些结果表明了新的猜想以及许多其他未解决的问题。这就需要寻找新的例子和额外的定理。