Wani Naiem Ahmad, Gupta Vivek Kumar, Kant Rajni, Aravinda Subrayashastry, Rai Rajkishor
Medicinal Chemistry Division, Indian Institute of Integrative Medicine, Canal Road, Jammu Tawi 180 001, India.
X-ray Crystallography Laboratory, Post-Graduate Department of Physics & Electronics, University of Jammu, Jammu Tawi 180 006, India.
Acta Crystallogr C Struct Chem. 2014 Jan;70(Pt 1):46-9. doi: 10.1107/S2053229613033044. Epub 2013 Dec 14.
The hybrid βγ dipeptide, methyl 2-[1-({2-[(tert-butoxycarbonyl)amino]benzamido}methyl)cyclohexyl]acetate (Boc-Ant-Gpn-OMe), C22H32N2O5, adopts a folded conformation stabilized by intramolecular six- (C6) and seven-membered (C7) hydrogen-bonded rings, together with weak C-H...O and C-H...π interactions, resulting in a ribbon-like structure.
杂合βγ二肽，2-[1-({2-[(叔丁氧羰基)氨基]苯甲酰胺基}甲基)环己基]乙酸甲酯（Boc-Ant-Gpn-OMe），C22H32N2O5，采用一种折叠构象，该构象通过分子内六元（C6）和七元（C7）氢键环以及弱的C-H...O和C-H...π相互作用得以稳定，从而形成一种带状结构。
