School of Material Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245, USA.
Phys Chem Chem Phys. 2014 Feb 21;16(7):2790-800. doi: 10.1039/c3cp53737d. Epub 2014 Jan 9.
The piezo-phototronic effect, a three way coupling effect of piezoelectric, semiconductor and photonic properties in non-central symmetric semiconductor materials, utilizing the piezo-potential as a "gate" voltage to tune the charge transport/generation/recombination and modulate the performance of optoelectronic devices, has formed a new field and attracted lots of interest recently. The mechanism was verified in various optoelectronic devices such as light emitting diodes (LEDs), photodetectors and solar cells etc. The fast development and dramatic increasing interest in the piezo-phototronic field not only demonstrate the way the piezo-phototronic effects work, but also indicate the strong need for further research in the physical mechanism and potential applications. Furthermore, it is important to distinguish the contribution of the piezo-phototronic effect from other factors induced by external strain such as piezoresistance, band shifting or contact area change, which also affect the carrier behaviour and device performance. In this perspective, we review our recent progress on piezo-phototronics and especially focus on pointing out the features of piezo-phototronic effect in four aspects: I-V characteristics; c-axis orientation; influence of illumination; and modulation of carrier behaviour. Finally we proposed several criteria for describing the contribution made by the piezo-phototronic effect to the performance of optoelectronic devices. This systematic analysis and comparison will not only help give an in-depth understanding of the piezo-phototronic effect, but also work as guide for the design of devices in related areas.
压光电效应是一种非中心对称半导体材料中压电、半导体和光子特性的三向耦合效应,利用压电势作为“门”电压来调节电荷输运/产生/复合,并调节光电设备的性能,最近形成了一个新领域并吸引了很多关注。该机制已在各种光电设备中得到验证,如发光二极管(LED)、光电探测器和太阳能电池等。压光电效应领域的快速发展和兴趣的急剧增加不仅展示了压光电效应的工作方式,也表明了对物理机制和潜在应用的进一步研究的强烈需求。此外,区分压光电效应与外部应变(如压阻、能带移动或接触面积变化)引起的其他因素的贡献非常重要,这些因素也会影响载流子行为和器件性能。在这方面,我们回顾了我们在压光电领域的最新进展,特别是着重指出了压光电效应在四个方面的特征:I-V 特性;c 轴取向;光照的影响;和载流子行为的调制。最后,我们提出了几个描述压光电效应对光电设备性能的贡献的标准。这种系统的分析和比较不仅有助于深入了解压光电效应,而且还可以为相关领域的设备设计提供指导。