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利用混合阳极结构在锂-硫电池中调控表面反应。

Manipulating surface reactions in lithium-sulphur batteries using hybrid anode structures.

机构信息

Pacific Northwest National Laboratory, Richland, Washington 99352, USA.

出版信息

Nat Commun. 2014;5:3015. doi: 10.1038/ncomms4015.

Abstract

Lithium-sulphur batteries have high theoretical energy density and potentially low cost, but significant challenges such as severe capacity degradation prevent its widespread adoption. Here we report a new design of lithium-sulphur battery using electrically connected graphite and lithium metal as a hybrid anode to control undesirable surface reactions on lithium. Lithiated graphite placed in front of the lithium metal functions as an artificial, self-regulated solid electrolyte interface layer to actively control the electrochemical reactions and minimize the deleterious side reactions, leading to significant performance improvements. Lithium-sulphur cells incorporating this hybrid anodes deliver capacities of >800 mAh g(-1) for 400 cycles at a high rate of 1,737 mA g(-1), with only 11% capacity fade and a Coulombic efficiency >99%. This simple hybrid concept may also provide scientific strategies for protecting metal anodes in other energy-storage devices.

摘要

锂硫电池具有高理论能量密度和潜在的低成本,但严重的容量衰减等重大挑战阻碍了其广泛应用。在这里,我们报告了一种使用电连接的石墨和锂金属作为混合阳极的锂硫电池的新设计,以控制锂上的不良表面反应。放置在锂金属前面的锂化石墨充当人工、自调节的固体电解质界面层,以主动控制电化学反应并最小化有害的副反应,从而显著提高性能。这种混合阳极的锂硫电池在 1737 mA g(-1)的高电流密度下循环 400 次后,仍能提供超过 800 mAh g(-1)的容量,容量衰减仅为 11%,库仑效率>99%。这种简单的混合概念也可能为保护其他储能设备中的金属阳极提供科学策略。

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