1-（2,3-二甲基苯基）哌嗪-1,4-二铵四氯合铜酸盐（II）
1-(2,3-Di-methyl-phen-yl)piperazine-1,4-diium tetra-chlorido-cuprate(II).
作者信息
Ben Mabrouk Safa, Ameur Iness, Abid Sonia, Rzaigui Mohamed
机构信息
Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Aug 10;69(Pt 9):m485. doi: 10.1107/S1600536813021454. eCollection 2013.
In the title salt, (C12H20N2)[CuCl4], the Cu(II) atom occupies a general position in a flattened tetra-hedral environment by Cl ligands, characterized by Cl-Cu-Cl angles of 134.04 (3) and 137.18 (4)°. The six-membered piperazinediium ring adopts a chair conformation. The organic cation and inorganic anion inter-act through N-H⋯Cl and C-H⋯Cl hydrogen bonds, forming a three-dimensional network.
在标题盐（C₁₂H₂₀N₂）[CuCl₄]中，Cu（II）原子通过Cl配体处于扁平四面体环境中的一般位置，其特征是Cl-Cu-Cl角为134.04（3）°和137.18（4）°。六元哌嗪二铵环呈椅式构象。有机阳离子和无机阴离子通过N-H⋯Cl和C-H⋯Cl氢键相互作用，形成三维网络。
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