• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

1-[2-(二乙基亚氮鎓基)乙基]-3-甲基咪唑四氯合铜酸盐(II)的晶体结构

Crystal structure of 1-[2-(di-ethyl-aza-n-ium-yl)eth-yl]-3-methyl-imidazolium tetra-chlorido-cuprate(II).

作者信息

Laus Gerhard, Kahlenberg Volker, Schottenberger Herwig

机构信息

University of Innsbruck, Faculty of Chemistry and Pharmacy, Innrain 80, 6020 Innsbruck, Austria.

University of Innsbruck, Institute of Mineralogy and Petrography, Innrain 52, 6020 Innsbruck, Austria.

出版信息

Acta Crystallogr E Crystallogr Commun. 2015 Apr 18;71(Pt 5):m110-1. doi: 10.1107/S2056989015006799. eCollection 2015 May 1.

DOI:10.1107/S2056989015006799
PMID:25995889
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4420035/
Abstract

The title compound, (C10H21N3)[CuCl4], is composed of one 1-[2-(di-ethyl-aza-nium-yl)eth-yl]-3-methyl-imidazolium dication and a tetra-chlorido-cuprate(II) dianion. The anion adopts a distorted tetra-hedral geometry. Bifurcated interionic N-H⋯Cl hydrogen bonds and several C-H⋯Cl contacts are observed, leading to a layer-like arrangement of the components parallel to (100).

摘要

标题化合物(C10H21N3)[CuCl4]由一个1-[2-(二乙铵基)乙基]-3-甲基咪唑鎓二价阳离子和一个四氯合铜(II)二价阴离子组成。阴离子采取扭曲的四面体几何构型。观察到分叉的离子间N-H⋯Cl氢键和几个C-H⋯Cl接触，导致各组分平行于(100)呈层状排列。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1786/4420035/df96110bbed6/e-71-0m110-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1786/4420035/c0d6b83ae68b/e-71-0m110-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1786/4420035/df96110bbed6/e-71-0m110-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1786/4420035/c0d6b83ae68b/e-71-0m110-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1786/4420035/df96110bbed6/e-71-0m110-fig2.jpg

相似文献

1
Crystal structure of 1-[2-(di-ethyl-aza-n-ium-yl)eth-yl]-3-methyl-imidazolium tetra-chlorido-cuprate(II).1-[2-(二乙基亚氮鎓基)乙基]-3-甲基咪唑四氯合铜酸盐(II)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Apr 18;71(Pt 5):m110-1. doi: 10.1107/S2056989015006799. eCollection 2015 May 1.
2
Acetonyltri-phenyl-phospho-nium 2,3,5-tri-phenyl-tetra-zolium tetra-chlorido-cuprate(II).丙酮基三苯基鏻四氯合铜（II）2,3,5-三苯基四唑鎓盐
Acta Crystallogr E Crystallogr Commun. 2018 Jan 1;74(Pt 1):69-71. doi: 10.1107/S205698901701800X.
3
Bis(2-methyl-pyridinium) tetra-chlorido-cuprate(II): synthesis, structure and Hirshfeld surface analysis.
Acta Crystallogr E Crystallogr Commun. 2021 Jun 25;77(Pt 7):726-729. doi: 10.1107/S2056989021006277. eCollection 2021 Jul 1.
4
Crystal structure of bis-(N,N,N',N'-tetra-methyl-guanidinium) tetra-chlorido-cuprate(II).双（N，N，N'，N'-四甲基胍鎓）四氯合铜酸盐（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Jun 24;72(Pt 7):1047-9. doi: 10.1107/S2056989016010161. eCollection 2016 Jul 1.
5
catena-Poly[[(5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro-cuprate(II)]-μ-chlorido].链状聚[[(5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂环十四碳-1,7-二烯)铜(II)]-μ-氯代-[二氯铜酸盐(II)]-μ-氯代]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m886-7. doi: 10.1107/S1600536812024932. Epub 2012 Jun 13.
6
Synthesis and crystal structure of 4-(2-ammonio-eth-yl)morpholin-4-ium di-chlorido-diiodido-cadmate/chlorido-tri-iodido-cadmate (0.90/0.10).4-(2-氨乙基)吗啉-4-鎓二氯二碘合镉酸盐/氯三碘合镉酸盐(0.90/0.10)的合成与晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Sep 5;72(Pt 10):1404-1407. doi: 10.1107/S2056989016013967. eCollection 2016 Oct 1.
7
Crystal structure of the monoclinic phase (phase IV) of bis-(tetra-methyl-ammonium) tetra-chlorido-cuprate(II).二（四甲基铵）四氯合铜（II）单斜相（IV相）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Feb 14;73(Pt 3):358-360. doi: 10.1107/S2056989017002146. eCollection 2017 Mar 1.
8
Crystal structure of the thermochromic bis-(di-ethyl-ammonium) tetra-chlorido-cuprate(II) complex.热致变色双（二乙铵）四氯合铜（II）配合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Jan 1;72(Pt 1):40-3. doi: 10.1107/S2056989015023348.
9
1-(2,3-Di-methyl-phen-yl)piperazine-1,4-diium tetra-chlorido-cuprate(II).1-（2,3-二甲基苯基）哌嗪-1,4-二铵四氯合铜酸盐（II）
Acta Crystallogr Sect E Struct Rep Online. 2013 Aug 10;69(Pt 9):m485. doi: 10.1107/S1600536813021454. eCollection 2013.
10
Bis[4-(di-methyl-amino)-pyridinium] tetra-chlorido-cuprate(II).二氯·双[4-(二甲基氨基)吡啶]合铜(II)酸盐
Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 19;69(Pt 11):m610-1. doi: 10.1107/S1600536813028006.

引用本文的文献

1
Acetonyltri-phenyl-phospho-nium 2,3,5-tri-phenyl-tetra-zolium tetra-chlorido-cuprate(II).丙酮基三苯基鏻四氯合铜（II）2,3,5-三苯基四唑鎓盐
Acta Crystallogr E Crystallogr Commun. 2018 Jan 1;74(Pt 1):69-71. doi: 10.1107/S205698901701800X.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.