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硝酸4-甲基苄基铵

4-Methyl-benzyl-ammonium nitrate.

作者信息

Gatfaoui Sofian, Marouani Houda, Rzaigui Mohamed

机构信息

Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Aug 21;69(Pt 9):o1453. doi: 10.1107/S1600536813022836. eCollection 2013.

DOI:10.1107/S1600536813022836
PMID:24427079
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3884420/
Abstract

In the title salt, C8H12N(+)·NO3 (-), the N atom of the 4-methyl-benzyl-ammonium cation is displaced by 1.366 (2) Å from the mean plane of the other atoms. In the crystal, the cations are connected to the anions by N-H⋯O and N-H⋯(O,O) hydrogen bonds, generating a layered network parallel to (100). A weak C-H⋯O inter-action also occurs.

摘要

在标题盐C₈H₁₂N⁺·NO₃⁻中,4-甲基苄基铵阳离子的N原子偏离其他原子的平均平面1.366 (2) Å。在晶体中,阳离子通过N—H⋯O和N—H⋯(O,O)氢键与阴离子相连,形成平行于(100)的层状网络。还存在弱的C—H⋯O相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20e9/3884420/89596d4f2857/e-69-o1453-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20e9/3884420/2774b0f57720/e-69-o1453-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20e9/3884420/88ca5ea504c1/e-69-o1453-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20e9/3884420/89596d4f2857/e-69-o1453-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20e9/3884420/2774b0f57720/e-69-o1453-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20e9/3884420/88ca5ea504c1/e-69-o1453-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20e9/3884420/89596d4f2857/e-69-o1453-fig3.jpg

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本文引用的文献

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2
Bis(4-methylbenzylammonium) tetrachloridozincate: a new noncentrosymmetric structure characterized by 13C CP-MAS NMR spectroscopy.双(4-甲基苄基铵)四氯锌酸盐:一种由13C CP-MAS NMR光谱表征的新型非中心对称结构。
Acta Crystallogr C. 2011 May;67(Pt 5):m126-9. doi: 10.1107/S0108270111012297. Epub 2011 Apr 13.
3
A short history of SHELX.SHELX简史。
反式-2,5-二甲基哌嗪-1,4-二铵二硝酸盐
Acta Crystallogr Sect E Struct Rep Online. 2014 May 31;70(Pt 6):o725. doi: 10.1107/S1600536814012100. eCollection 2014 Jun 1.
4
Dopaminium nitrate.硝酸多巴胺
Acta Crystallogr Sect E Struct Rep Online. 2014 Apr 18;70(Pt 5):o571-2. doi: 10.1107/S1600536814008265. eCollection 2014 May 1.
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m-Xylylenediaminium dinitrate.间苯二甲撑二胺二硝酸盐
Acta Crystallogr Sect E Struct Rep Online. 2014 Mar 5;70(Pt 4):o398-9. doi: 10.1107/S1600536814004620. eCollection 2014 Apr 1.
6
1,1,4,7,7-Penta-methyl-diethylenetri-ammonium trinitrate.1,1,4,7,7-五甲基二亚乙基三铵三硝酸酯
Acta Crystallogr Sect E Struct Rep Online. 2014 Jan 25;70(Pt 2):o198. doi: 10.1107/S1600536814001469. eCollection 2014 Feb 1.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.