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包层剥离法:在柔韧超薄塑料薄膜中制作碳纳米管 CMOS 集成电路。

Encapsulate-and-peel: fabricating carbon nanotube CMOS integrated circuits in a flexible ultra-thin plastic film.

机构信息

NOVITAS, Nanoelectronics Centre of Excellence, School of Electrical and Electronic Engineering, Nanyang Technological University, 639798 Singapore, Singapore.

出版信息

Nanotechnology. 2014 Feb 14;25(6):065301. doi: 10.1088/0957-4484/25/6/065301. Epub 2014 Jan 17.

Abstract

Fabrication of single-walled carbon nanotube thin film (SWNT-TF) based integrated circuits (ICs) on soft substrates has been challenging due to several processing-related obstacles, such as printed/transferred SWNT-TF pattern and electrode alignment, electrical pad/channel material/dielectric layer flatness, adherence of the circuits onto the soft substrates etc. Here, we report a new approach that circumvents these challenges by encapsulating pre-formed SWNT-TF-ICs on hard substrates into polyimide (PI) and peeling them off to form flexible ICs on a large scale. The flexible SWNT-TF-ICs show promising performance comparable to those circuits formed on hard substrates. The flexible p- and n-type SWNT-TF transistors have an average mobility of around 60 cm(2) V(-1) s(-1), a subthreshold slope as low as 150 mV dec(-1), operating gate voltages less than 2 V, on/off ratios larger than 10(4) and a switching speed of several kilohertz. The post-transfer technique described here is not only a simple and cost-effective pathway to realize scalable flexible ICs, but also a feasible method to fabricate flexible displays, sensors and solar cells etc.

摘要

在软基底上制造基于单壁碳纳米管薄膜(SWNT-TF)的集成电路(IC)一直具有挑战性,因为存在一些与加工相关的障碍,例如印刷/转移的 SWNT-TF 图案和电极对准、电极/通道材料/介电层的平整度、电路对软基底的附着等。在这里,我们报告了一种新方法,通过将硬基底上预先形成的 SWNT-TF-IC 封装在聚酰亚胺(PI)中,并将其剥离,从而在大规模上形成柔性 IC,规避了这些挑战。柔性 SWNT-TF-IC 表现出与在硬基底上形成的电路相当的有前景的性能。柔性 p 型和 n 型 SWNT-TF 晶体管的平均迁移率约为 60 cm(2) V(-1) s(-1),亚阈值斜率低至 150 mV dec(-1),工作栅极电压小于 2 V,开关比大于 10(4),开关速度可达几千赫兹。这里描述的后转移技术不仅是实现可扩展柔性 IC 的简单且具有成本效益的途径,也是制造柔性显示器、传感器和太阳能电池等的可行方法。

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