[1,1'-双（二苯基膦基）钴鎓-κ(2) P,P'](η(5)-环戊二烯基){2-[4-(4-乙炔基苯基)苯基]乙炔基-κC}钌(II) 六氟磷酸酯
[1,1'-Bis(di-phenyl-phosphan-yl)cobalto-cenium-κ(2) P,P'](η(5)-cyclo-penta-dien-yl){2-[4-(4-ethynylphen-yl)phen-yl]ethynyl-κC}ruthenium(II) hexa-fluorido-phosphate.
作者信息
Zeng Ling-Zhen, Wu Yun-Ying, Tian Guang-Xuan, Li Zhen
机构信息
College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, People's Republic of China.
College of Resources and Environment, Yuxi Normal University, Kunming 653100, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 19;69(Pt 11):m607. doi: 10.1107/S1600536813028195.
In the title compound, [CoRu(C5H5)(C16H9)(C17H14P)2]PF6, the Ru(II) atom is coordinated by a cyclo-penta-dienyl ring in an η(5)-mode, one C atom from a 4,4'-diethynyl-1,1'-biphenyl ligand and two P atoms from a chelating 1,1'-bis-(di-phenyl-phosphan-yl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C-H⋯F hydrogen bonds link the complex cations and hexa-fluorido-phosphate anions into a three-dimensional supra-molecular structure.
在标题化合物[CoRu(C₅H₅)(C₁₆H₉)(C₁₇H₁₄P)₂]PF₆中，Ru(II)原子由一个环戊二烯基环以η(5)模式配位，一个碳原子来自4,4'-二乙炔基-1,1'-联苯配体，两个磷原子来自螯合的1,1'-双（二苯基膦基）钴茂配体，形成一个三腿钢琴凳几何构型。在晶体中，弱的C-H⋯F氢键将配合物阳离子和六氟磷酸根阴离子连接成三维超分子结构。
Zotero 插件