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Preparation and Structural Properties of In-H Complexes.铟配合物的制备及其结构性质
Polyhedron. 2013 Jul 13;58:65-70. doi: 10.1016/j.poly.2012.07.098.
2
Heterobimetallic Complexes with M-(OH)-M Cores (M = Fe, Mn, Ga; M = Ca, Sr, and Ba): Structural, Kinetic, and Redox Properties.具有M-(OH)-M核（M = Fe、Mn、Ga；M = Ca、Sr和Ba）的异双金属配合物：结构、动力学和氧化还原性质
Chem Sci. 2013 Feb;4(2):717-726. doi: 10.1039/C2SC21400H.
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Catalytic conversion of nitrogen to ammonia by an iron model complex.铁模型配合物催化氮气转化为氨。
Nature. 2013 Sep 5;501(7465):84-7. doi: 10.1038/nature12435.
4
Unsymmetrical bimetallic complexes with M(II)-(μ-OH)-M(III) cores (M(II)M(III) = Fe(II)Fe(III), Mn(II)Fe(III), Mn(II)Mn(III)): structural, magnetic, and redox properties.具有 M(II)-(μ-OH)-M(III) 核的不对称双金属配合物（M(II)M(III) = Fe(II)Fe(III)、Mn(II)Fe(III)、Mn(II)Mn(III)）：结构、磁性和氧化还原性质。
Inorg Chem. 2013 Sep 16;52(18):10229-31. doi: 10.1021/ic401561k. Epub 2013 Aug 30.
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Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron.近期钼和铁对氮气的均相还原的进展。
Nat Chem. 2013 Jul;5(7):559-65. doi: 10.1038/nchem.1620. Epub 2013 May 26.
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Conversion of Fe-NH2 to Fe-N2 with release of NH3.将 Fe-NH2 转化为 Fe-N2 并释放 NH3。
J Am Chem Soc. 2013 Jan 16;135(2):534-7. doi: 10.1021/ja307714m. Epub 2013 Jan 8.
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Assembly and properties of heterobimetallic Co(II/III)/Ca(II) complexes with aquo and hydroxo ligands.偕同水和羟基数配体的异双核 Co(II/III)/Ca(II) 配合物的组装与性质。
J Am Chem Soc. 2012 Oct 24;134(42):17526-35. doi: 10.1021/ja304525n. Epub 2012 Oct 15.
8
A five-coordinate phosphino/acetate iron(II) scaffold that binds N2, N2H2, N2H4, and NH3 in the sixth site.一个五配位的膦/乙酸根铁(II)支架，可在第六位结合 N2、N2H2、N2H4 和 NH3。
Inorg Chem. 2011 Nov 21;50(22):11285-7. doi: 10.1021/ic2016066. Epub 2011 Oct 17.
9
The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core.氧化还原非活性金属离子对氧气活化的影响：含 Mn(III)-(μ-OH)-Ca(II)核的异双核配合物的分离与表征。
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10
Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.通过氧化还原诱导的配位 NH3 和 N2 硅烷化的排出，在三角双锥铁上触发 N(2)的摄取。
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三齿磺酰胺配体负载的 Fe(II/III)-NH3 配合物的合成、结构和反应性。

Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand.

机构信息

Department of Chemistry, University of California-Irvine, 1102 Natural Sciences II, Irvine, CA 92697, USA.

出版信息

Chem Commun (Camb). 2014 Mar 7;50(19):2515-7. doi: 10.1039/c3cc48804g. Epub 2014 Jan 24.

DOI:10.1039/c3cc48804g
PMID:24457593
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3954711/
Abstract

Complexes M(n)MST(NH3) (M(n) = Fe(II), Fe(III), Ga(III)) were prepared and each contains an intramolecular hydrogen bonding network involving the ammonia ligand. Deprotonation of the Fe(III)-NH3 complex afforded a putative Fe(III)MST(NH2) species whose reactivity has been explored.

摘要

配合物M(n)MST(NH3)（M(n) = Fe(II), Fe(III), Ga(III))被制备出来，每个配合物都包含一个涉及氨配体的分子内氢键网络。Fe(III)-NH3 配合物的去质子化生成了一种假定的Fe(III)MST(NH2)物种，其反应性已被探索。