有机合成中的牛烷类
Oxenoids in organic synthesis.
机构信息
The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion - Israel Institute of Technology, Haifa 320008, Israel.
出版信息
Org Biomol Chem. 2014 Mar 14;12(10):1535-46. doi: 10.1039/c3ob42349b.
Experimental and theoretical studies of metalated peroxides confirmed their unique properties as oxenoids (electrophilic oxidants) allowing for a highly selective and efficient oxidation processes of nucleophilic organometallic species. In this short review we present the most prominent examples of the application of this class of reagents towards organic synthesis.
金属过氧化物的实验和理论研究证实了它们作为氧代试剂（亲电氧化剂）的独特性质，可实现亲核有机金属物种的高度选择性和高效氧化过程。在这篇简短的综述中，我们介绍了此类试剂在有机合成中应用的最突出实例。
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