Department of Chemistry, Yonsei University, Seoul 120-749, Korea.
Chem Commun (Camb). 2014 Mar 21;50(23):3078-80. doi: 10.1039/c4cc00126e.
Two meso-meso vinylene-bridged Zn(II) porphyrin dimers and were analyzed in terms of the control of their conformational dynamics induced by the rotation around the double bond bridge. The dihedral angles between the two porphyrin rings were modulated through coordination with α,ω-diaminoalkanes of varying chain lengths.
两个间-间亚乙烯基桥联的锌(II)卟啉二聚体被分析，以控制由双键桥旋转引起的构象动力学。两个卟啉环之间的二面角通过与不同链长的α,ω-二氨基烷烃配位进行调节。
