5,5,7,12,12,14-六甲基-1,8-双-(4-硝基苄基)-1,4,8,11-四氮杂环十四烷
5,5,7,12,12,14-Hexamethyl-1,8-bis-(4-nitro-benz-yl)-1,4,8,11-tetra-aza-cyclo-tetra-deca-ne.
作者信息
Gayathri K, Sathya S, Usha G, Ramanjaneya Reddy G, Balasubramanian S
机构信息
PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India.
Department of Inorganic Chemistry, University of Madras, Maraimalai Campus, Chennai-25, Tamilnadu, India.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Dec 14;70(Pt 1):o50. doi: 10.1107/S1600536813031164. eCollection 2014 Jan 1.
The asymmetric unit of the title compound, C30H46N6O4, contains one half-mol-ecule. The C(benzene)-C(CH2)-N-C(-Me) torsion angle is -79.89 (13)° suggesting a synclinal orientation of the nitro-benzene ring with respect to the macrocycle. The conformation of the macrocycle is stabilized by intra-molecular N-H⋯N hydrogen bonds.
标题化合物C30H46N6O4的不对称单元包含半个分子。C(苯环)-C(亚甲基)-N-C(-甲基)扭转角为-79.89 (13)°，表明硝基苯环相对于大环呈顺错取向。大环的构象通过分子内N-H⋯N氢键得以稳定。
Zotero 插件