双 C(sp3)-H 键功能化介导的顺序氢化物转移/环化过程：多杂环的非对映选择性构建。
Double C(sp3)-H bond functionalization mediated by sequential hydride shift/cyclization process: diastereoselective construction of polyheterocycles.
机构信息
Department of Chemistry, Faculty of Science, Gakushuin University , Mejiro, Toshima-ku, Tokyo 171-8588, Japan.
出版信息
J Am Chem Soc. 2014 Mar 12;136(10):3744-7. doi: 10.1021/ja412706d. Epub 2014 Mar 3.
PMID:24564435
Abstract
Described herein are two novel types of double C(sp(3))-H bond functionalizations triggered by a sequential hydride shift/cyclization process: (1) construction of a bicyclo[3.2.2]nonane skeleton by a [1,6]- and [1,5]-hydride shift sequence and (2) sequential [1,4]- and [1,5]-hydride shift mediated construction of a linear tricyclic skeleton.
摘要
本文描述了两种新型的双 C(sp(3))-H 键官能化反应，它们是由顺序的氢化物转移/环化过程引发的：（1）通过 [1,6]-和 [1,5]-氢化物转移序列构建双环[3.2.2]壬烷骨架；（2）通过顺序的 [1,4]-和 [1,5]-氢化物转移介导构建线性三环骨架。
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