Department of Chemical and Biological Engineering, University at Buffalo (SUNY), 310 Furnas Hall, Buffalo, New York, 14260-4200 USA.
Chem Soc Rev. 2014 Jun 7;43(11):3908-20. doi: 10.1039/c3cs60417a. Epub 2014 Feb 24.
The creation and study of non-metallic nanomaterials that exhibit localized surface plasmon resonance (LSPR) interactions with light is a rapidly growing field of research. These doped nanocrystals, mainly self-doped semiconductor nanocrystals (NCs) and extrinsically-doped metal oxide NCs, have extremely high concentrations of free charge carriers, which allows them to exhibit LSPR at near infrared (NIR) wavelengths. In this tutorial review, we discuss recent progress in developing and synthesizing doped semiconductor and metal oxide nanocrystals with LSPR, and in studying the optical properties of these plasmonic nanocrystals. We go on to discuss their growing potential for advancing biomedical and optoelectronic applications.
具有局域表面等离激元共振(LSPR)与光相互作用的非金属纳米材料的创造和研究是一个快速发展的研究领域。这些掺杂纳米晶体,主要是自掺杂半导体纳米晶体(NCs)和外掺杂金属氧化物 NCs,具有极高浓度的自由电荷载流子,这使得它们能够在近红外(NIR)波长处表现出 LSPR。在本教程综述中,我们讨论了在开发和合成具有 LSPR 的掺杂半导体和金属氧化物纳米晶体以及研究这些等离子体纳米晶体的光学性质方面的最新进展。我们接着讨论了它们在推进生物医学和光电应用方面的巨大潜力。