Polińska P, Gillig C, Wittmer J P, Baschnagel J
Institut Charles Sadron, Université de Strasbourg & CNRS, 23 rue du Loess, 67034, Strasbourg Cedex, France.
Eur Phys J E Soft Matter. 2014 Feb;37(2):12. doi: 10.1140/epje/i2014-14012-7. Epub 2014 Feb 27.
Conformational properties of regular dendrimers and more general hyperbranched polymer stars with Gaussian statistics for the spacer chains between branching points are revisited numerically. We investigate the scaling for asymptotically long chains especially for fractal dimensions df = 3 (marginally compact) and df = 2.5 (diffusion limited aggregation). Power-law stars obtained by imposing the number of additional arms per generation are compared to truly self-similar stars. We discuss effects of weak excluded-volume interactions and sketch the regime where the Gaussian approximation should hold in dense solutions and melts for sufficiently large spacer chains.
对具有高斯统计特性的规则树枝状大分子以及分支点之间间隔链更为一般的超支化聚合物星型结构的构象性质进行了数值重新研究。我们研究了渐近长链的标度,特别是对于分形维数(d_f = 3)(临界致密)和(d_f = 2.5)(扩散受限聚集)的情况。将通过规定每一代额外臂数得到的幂律星型结构与真正的自相似星型结构进行了比较。我们讨论了弱排斥体积相互作用的影响,并勾勒出在足够大的间隔链的致密溶液和熔体中高斯近似应该成立的范围。