CCNU-OttawaU Joint Research Centre, Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079 (China); Collaborative Innovation Center of Chemical Science and Engineering, Tianjin (China).
Angew Chem Int Ed Engl. 2014 Apr 14;53(16):4038-40. doi: 10.1002/anie.201400018. Epub 2014 Mar 5.
New players in town: In situ generated transition-metal-containing carbonyl ylides are a unique class of reagents which have found wide applications in catalytic asymmetric cascade reactions. Recent advances in reaction design are likely to lead to more novel developments with these reactive species.
在原地生成的含过渡金属的羰基叶立德是一类独特的试剂,在催化不对称级联反应中得到了广泛的应用。反应设计的最新进展可能会使这些反应性物质有更多新颖的发展。