Direct olefination of fluorinated benzothiadiazoles: a new entry to optoelectronic materials.

作者信息

Xiao Yu-Lan, Zhang Bo, He Chun-Yang, Zhang Xingang

机构信息

Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, CAS, 345 Lingling Lu, Shanghai 200032 (P. R. China), Fax: (+86) 21-64166128.

出版信息

Chemistry. 2014 Apr 14;20(16):4532-6. doi: 10.1002/chem.201400075. Epub 2014 Mar 12.

DOI:10.1002/chem.201400075

PMID:24623462

Abstract

Fluorinated olefin-containing benzothiadiazoles have important applications in optoelectronic materials. Herein, we reported the direct olefination of fluorinated benzothiadiazoles, as catalyzed by palladium. The reaction proceeds under mild reaction conditions and shows high functional-group compatibility. A preliminary study of the properties of the resulting symmetrical and unsymmetrical olefin-containing fluorinated benzothiadiazoles in red-light-emitting dyes has also been conducted.

摘要