氟代苯并噻二唑和苯并三唑与（杂）芳基碘的直接芳基化反应。

Direct (het)arylation of fluorinated benzothiadiazoles and benzotriazole with (het)aryl iodides.

机构信息

College of Chemistry, Chemical Engineering and Biotechnology, Donghua University , 2999 North Renmin Lu, Shanghai 201620, China.

出版信息

J Org Chem. 2014 Feb 21;79(4):1712-8. doi: 10.1021/jo402675v. Epub 2014 Feb 7.

DOI:10.1021/jo402675v

PMID:24475913

Abstract

A new and controllable method for the preparation of unsymmetrical and symmetrical fluorinated benzothiadiazole (FBT)-arene structures that can be applied in organic optoelectronic materials has been developed. The reaction proceeds under mild reaction conditions with high efficiency and shows excellent functional group compatibility, even toward bromide. Fluorinated benzotriazoles also take part in the reaction.

摘要

开发了一种新的、可控制的方法，用于制备不对称和对称的氟化苯并噻二唑（FBT）-芳基结构，这些结构可应用于有机光电材料中。该反应在温和的反应条件下进行，具有高效率，并显示出优异的官能团相容性，甚至对溴化物也有很好的相容性。氟化苯并三唑也参与了反应。